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Yes its unsafe if for no other reason than some of those rounds could end up in a regular 38 special and create a hazardous situation.
Another reason is the pressures will be higher in the 38 case because of reduced capacity, meaning what you load in a 357 case safely can be unsafe just because of the diminished case capacity. Almost no load will fill up to capacity a 38special case. It was originally designed for black powder.
It is a bad idea on many levels so stick with the 357 cases, but big cudos to you for asking first.
whup, beat me Bob! Woulda been easier to type +1 on my phone.
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