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I will chip in.
If I am correct a whitetail is about the same size as the fallow deer we have here.
Hard to beat a 130g Speer Hot Cor, Hornady Interlock, Sierra Pro Hunter or similar over a charge of around 54g of H4350 (which is known here as AR2209) with a standard primer. You should work up to this load from a couple of grains below.
It will fix up a deer.
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