I think it's chemically induced corrosion from a contaminant. Could be something as simple as sweat from your hands or a multitude of other possibilities. Chlorides are bad for copper and its alloys:
https://en.wikipedia.org/wiki/Bronze_disease
I have some ammo I loaded 20 years ago that is starting to show some tarnished spots on the outside, but upon dismantling the worst round, I found all was clean and shiny on the inside. Some ammo can go horribly bad on the inside in an alarmingly short time, due to destabilized powder.