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The Walker was, by design, engineered to fire 60 grains of powder under a conical bullet. NOT a 140 grain round ball.
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Assuming that the replica cylinders are accurately sized, there's no way you'd get 60 grains under one of the pickets that were supplied with the Walkers. I can't even quite get 60 under a .457 ball, about 58 is the best I can do.