He certainly didn't hit the guy in the brain or the guy wouldn't have stayed on his feet and making voluntary movements.
The first shot does appear to have hit the hood of the robber's jacket and may have touched meat under the hood, but had to have missed the brain.
The second shot may have touched meat too, but again, it missed the brain because the man stayed on his feet and his body remained under voluntary control.
The immediate reaction when the third shot connects makes it pretty obvious that the brain was hit.
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