Those barrels are machined with a slightly larger diameter band of metal around the barrel at the muzzle.
This article contains a picture of one with the band of metal visible.
https://www.gunsamerica.com/digest/r...stol-need-one/
Here's the picture. The PX4 barrel is the one at the bottom.
I suspect that what your fingernail is catching on is the edge of that band.