Of the two powders you mention, HS6 and Tite Group, I'd say Tite Group would be best. Branching out, WST is worth a try. I use TG on .45acp, .38 Spcl and .32acp. Have for years. It's a touch on the dirty side with light loads, but not as dirty as Bullseye in my experiences. I notice no difference between large and small primers. Since you have experience reloading .32acp, you'll love reloading .45acp. I have small hands, but still feel like I have five thumbs when it comes to working with .32acp. The size of .45acp is so much easier to work with.
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