I highly recommend nickel-plated ammo, I've seen plain brass degrade pretty quickly in a hot humid car.
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Just my opinion, of course, but I think there is a lot bigger problem with leaving a gun in your car than the thing melting or the powder degrading. That's risking having the darn thing stolen. Lose the gun, that's tough. Lose the gun and someone uses it to kill someone, um, that's really tough. And I think if you leave a gun in a car you're partially responsible if something horrible like that happens.
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Nonsense, stop blaming yourself for someone else's propensity to commit a crime. Locking your car is the same as locking your home.