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1. Will it hurt to take the bluing out of the inside of the barrel and cylinder chambers?
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As was said, there is no bluing inside the chambers or barrel of any gun that has been fired.
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2. Will the gun in this state rust very easily, would I have to be more care worthy with it?
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Yes. Bluing is a protective oxide layer that helps protect against rust. You will now have raw exposed steel. You will need to keep the firearm well oiled.
Steve