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Old October 26, 2009, 08:44 PM   #14
Shoney
Senior Member
 
Join Date: February 21, 2002
Location: Transplanted from Montana
Posts: 2,311
SL1

Just curious. Did you overlook my statement in my first post on this subject? Where I stated:
Quote:
pV=nRT

where

p is the absolute pressure [Pa],
V is the volume [m3] of the vessel containing the moles of gas, here it is the volume you allow in the shell case, determined by how deep the bullet is seated
n is the amount of substance of gas [mol], here it is in solid form as powder
R is the gas constant [8.314 472 m3•Pa•K−1•mol−1],
T is the temperature in kelvin [K].

This is a gross oversimplification, because as the bullet moves down the barrel, the volume and pressure are constantly changing.
There was no attempt to predict pressures, only show in very simple mathmatical terms, why the powder charge is lowered for heavier weight bullets.

If as you say:
Quote:
The main reason that the prefect gas law doesn't work here is - - -
Then pray tell, what laws are used to compute this?????

If it is not a complex form of the pV=nRT; taking into accout the changing pressures and changing volumes and changing amounts of gas at changing temperatures???? What is the basic formula that is used??????
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