"Imagine a pin holding a striker rusting through, let's say."
As far as I know, no civil war munitions used a spring-loaded striker.
Even if they did, and corrosion were a factor, it's far more likely that the spring would have corroded to uselessness long before any safety pin would have corroded through.
The most typical civil war era mechanical fuse would have been inertial, firing upon impact with the target, which would mean a rifled gun and oblong shell, not a roundball.
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"The gift which I am sending you is called a dog, and is in fact the most precious and valuable possession of mankind" -Theodorus Gaza
Baby Jesus cries when the fat redneck doesn't have military-grade firepower.
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