I see nothing wrong with loading .44Sp loads in your .44Mag brass. I do the same thing with .357, and it works just fine. A good reason to do this is because you won't have the build-up from the shorter .44Sp case in the cylinders. If you shoot a lot of .44Sp (or .38Sp in a .357), you can build up a ring of "crud" in the cylinders that takes a lot of scrubbing to remove, and the longer rounds won't chamber properly without totally cleaning it out.
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