If the gun is in operating condition (action, trigger and hammer all work, stocks are not falling off) give it a good cleaning and it should be fine to shoot. The ammo I'd be very careful about. If your attic gets really hot in the summer that could cause issues with the powder over such a long period of time.
If the ammo is in their original boxes they may have some collectors value to them, depending on condition of course. Also you may want to do a google search for "pre 1964 model 94" and read up on your rifle, they are considered much better than those produced after 1964.
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