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Are you using factory ammo? If you're using reloads they may be sized incorrectly and preventing the slide from going into battery when the chamber becomes foaled. It could also be the extractor. If the round is in front of the extractor (Glock pistols will, and do, fire slightly out of battery), this may explain the off center primer hits. As to why the brass would still eject, the blowback would cause the brass to strike the ejector and exit as you would expect.
I would try several other factory loads. If the problem persists, unload and clear the weapon and take it to a gunsmith. Or call Glock to get their feedback.
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~Blades~
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