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Entirely possible with any double barrel double trigger gun (if both hammers are cocked).
BAD IDEA
Dramatic, but STUPID.
(which is why they do it so often in movies and other fiction)
Double the recoil (and even if not exactly firing in the same microsecond) its close enough together to be felt as one double strength jolt.
If you are foolish enough to do it from the hip, odds are real high you'll get your fingers bashed.
Tactically speaking, if one shot doesn't do it, firing your only other shot at the same instant, probably won't, either, and worse, then you're "out" until you reload.
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All else being equal (and it almost never is) bigger bullets tend to work better.
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