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Whats the biggest caliber and in the best make and model that is still good accuracy at say 50 yards?
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Career makes an airgun in 9mm (Korean air gun). Now, those 9mm pellets are not nearly the same weight as a 9mm handgun bullet, but they are pretty hefty for an airgun - can be used for hunting game. Quackenbush makes a .50 caliber air rifle; again, I don't know the grain of the actual .50 cal pellet.
http://www.quackenbushairguns.com/bandit_1.html