Round shot of uniform size is about 60% as dense as a solid lead slug filling the same cylinder (with free-running shot, IE "not jammed" because the balls are too big to shake into position this ratio is fixed and is not changed by changing ball size).
Thus: Your shot load can take up a "little more" depth in the chamber than a round ball does, and be of the same weight.
For snakes... smaller is likely better. Can #12 shot be bought (snake shot size for a .22)?
Clem: That's one big Moccasin! How did it fry up? ;-)
Willie
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