As said earlier, it will probably get you on paper.
Your rifle and you are a dynamic system under recoil. The energy input is different between a 22 LR and a .223 so I would not expect the bullets to print to the same point of aim.
However I have never done this, the 223 is a lot lighter recoil than a 308 or 270, so, let us know just how close it is when you do get zero'd.
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If I'm not shooting, I'm reloading.
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