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As you say your new to reloading rifle and handgun loads, I would suggest you do try some different powders, to see if there is a sweet spot of bullet, powder, primer combination. The primers are another item you should experiment with. They do make a difference in accuracy. But as the other posters stated the load in the 06 with 4895 would be hard to beat. I can't help you with the 454 as I have never owned one. But In my 44 mags I have always leaned on H110. I've tried Bluedot, 2400, and a couple others over the years, but always go back to H110.
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