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Consistency is consistency, so the most accurate load at 100yds has the theoretical potential to be the most accurate at 600yds. However, the longer the distance the more the bullet will be affected by wind. Thus if you develop a load with a low ballistic coefficient and it shoots well at 100yds, it might actually be harder to get as good of accuracy out of it at longer ranges (because the more the bullet is affected by the wind, the more variance there will be in exactly how much it's affected). Thus if you're planning on long range it would be best to work up a load using a bullet with a high ballistic coefficient.
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