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This is NOT the proper way, but i removed the nipple, dumped the powder, measured another charge, then fired it.
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This might not work if he's using pellets. What I do (also may not be the proper way) is remove the nipple, put one third of a pinch of powder under it, then put the nipple back in and fire again. If you didn't forget to put powder under the ball, it will probably fire.
EDIT: also pick out the nipple.
If you already left the range/hunting area, I think you need to ball puller or the CO2 discharger:
http://www.cabelas.com/cabelas/en/te...824&id=0006480