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Can pyrodex pellets be used with them?
Sure can. I like the "devil's breath" of real BP myself over pyrodex. BP is supposed to be a lot of smoke and nasty stench. YMMV.
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IIRC, Hodgdon's is no longer making Pyrodex. "777" is the newest BP substitute from Hodgdon's. I assume that they will pelletize it for the .50 cal muzzleloaders, but I don't think that the .44 cal pellets wil be manufactured.