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Oleg,
Check around your local sporting goods stores and look for "Snake-Chaps". They're chaps that strap onto your legs, covering the tops of your boots, all the way up to the crotch. They are made of out of a durable material that snakes can't bite through.
Their downfall -- They're a bit bulky, stiff, and extremely hot when worn during the warmer months. But which is the better case scenario? Dead or uncomfortable?
About shot placement on the snake. I believe if a person has to kill something, is should be done in a humane manner. So any other shot besides the headshot, would not be an option.
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